A :: B :: C :: D :: E :: F :: G :: H :: I :: J :: K :: L :: M :: N :: O :: P :: Q :: R :: S :: T :: U :: V :: W :: X :: Y :: Z :: Extras :: Links :: perso ::

   SAKURAI-HOSOMI reaction




mechanism:



remarks:
  • Silicon stabilizes b-carbocations (b effect)
  • Lewis acid-promoted allylation of various electrophiles with allyltrimethylsilane

references:

J. Org. Chem. 2006, 71, 8516.
J. Am. Chem. Soc. 2005, 127, 14556.
Org. Lett. 2003, 5, 55.
J. Am. Chem. Soc. 2002, 124, 6536.
Org. Lett. 2002, 4, 1047.