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   BAEYER-VILLIGER rearrangement

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mechanism:

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  • works with H2O2 under basic conditions as well.
  • the most electron-rich group migrates
  • the migrating group retains its stereochemistry

example:

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  • higher priority than alkene epoxidation

references:

J. Org. Chem. 2008, 73, 3996.
J. Org. Chem. 2007, 72, 3031.
Org. Lett. 2006, 8, 1763.
J. Org. Chem. 2004, 69, 7148.
J. Org. Chem. 1994, 59, 3123.
J. Org. Chem. 1993, 58, 4516.
Organic Reactions 1993, 43, 251.
J. Am. Chem. Soc. 1953, 75, 2318.