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   SHARPLESS Asymmetric Epoxidation (SAE)


mechanism:

 

references:

Tetrahedron: Asymmetry 2007, 18, 149.
J. Org. Chem. 2004, 69, 2042.
Angew. Chem., Int. Ed. Engl. 2002, 41, 2024. (review)
Synthesis 1986, 89.
J. Am. Chem. Soc. 1980, 102, 5974. (seminal)